An algorithm of optimal distribution of equipment for fire stations

 

Oleksii Basmanov

National University of Civil Defenсe of Ukraine

http://orcid.org/0000-0002-6434-6575

 

Saveliev Dmytro

National University of Civil Defenсe of Ukraine

http://orcid.org/0000-0002-4310-0437

 

Melezhyk Roman

National University of Civil Defenсe of Ukraine

http://orcid.org/0000-0001-6425-4147

 

Lutsenko Tatiana

National University of Civil Defenсe of Ukraine

http://orcid.org/0000-0001-7373-4548

 

DOI: https://doi.org/10.52363/2524-0226-2023-38-12

 

Keywords: local territory, level of danger, functional capacity, service area, location of fire stations

 

Аnnotation

The object of the study is the process of functioning of fire stations, and the subject of the study is the distribution of equipment between units serving a certain area. An algorithm of the optimal distribution of equipment for fire stations was built. In practice, it opens up opportunities to reduce the time it takes for firefighting units to reach the place of call by changing the service areas of the units. The model is based on the assumption of the sufficiency of forces and means in fire stations to carry out rescue operations and eliminate fires in the area of their service. The model is based on the division of the entire area of responsibility into separate sub-areas or the selection of individual objects for which a list of possible emergency situations related to fires, their frequency, forces and means necessary for their elimination is known. The task of optimally determining the area of responsibility of rescue units is formulated. The optimization criterion is the minimum time for units to follow from the location to the place of call. The objective function includes both the follow-up time and the number of units of equipment involved in eliminating the accident. This allows you to take into account the complexity of the emergency situation, since more complex situations will require the involvement of a larger number of equipment and units. The limitations of the task are determined by the available forces and means in operational and rescue units. An algorithm for the optimal distribution of equipment between existing operational and rescue units has been built. It is shown that the domain of admissible solutions is convex. The built model can be used to determine the service areas of already existing fire stations, as well as when choosing the locations of additional fire stations.

 

References

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A model of random pulsations of radiant heat flow from a flammable liquid fire

 

Popov Oleksandr

Center for Information-analytical and Technical

Support of Nuclear Power Facilities Monitoring

of the NAS of Ukraine

https://orcid.org/0000-0002-5065-3822

 

Danilin Oleksandr

National University of Civil Defence of Ukraine

http://orcid.org/0000-0002-4474-7179

 

Petukhova Olena

National University of Civil Defence of Ukraine

http://orcid.org/0000-0002-4832-1255

 

Borodych Pavlo

National University of Civil Defence of Ukraine

http://orcid.org/0000-0001-9933-8498

 

DOI: https://doi.org/10.52363/2524-0226-2023-38-11

 

Keywords: spill fire, fire in the tank farm, thermal effect of fire, heat exchange

 

Аnnotation

 

The object of the study is the process of liquid combustion in a tank or in a spill. Unlike the standard approach that assumes the shape of the flame is constant, random pulsations of the flame due to the turbulent mode of liquid combustion are considered. The pulsations lead to the random nature of the mutual radiation coefficient and the temperature of the radiating surface of the flame. This leads to a random value of the radiant heat flux density from the fire. Using the central limit theorem allows justifying the assumption about the normal law of the distribution of the radiant heat flux density, the mutual radiation coefficient and the temperature of the radiating surface of the flame. The assumption of a normal distribution law allows calculating the mathematical expectation of the heat flux density. It is shown that the average value of the heat flux density increases with an increase in the dispersion of the temperature of the radiating surface and the coefficient of mutual radiation, as well as with an increase in the correlation coefficient between them. It means that neglecting random flame pulsations can lead to underestimates of the average heat flux density from a fire. The dispersion of the radiant heat flux density was found and it was shown that it increases with the growth of the dispersion of the flame temperature and the mutual radiation coefficient. The standard deviation of the heat flux density can be more than 40 % of its average value if the standard deviations of the flame temperature and the mutual radiation coefficient are up to 10 % of their average values. The obtained results can be used to clarify the thermal effect of a liquid fire on neighboring objects.

 

References

 

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  3. Yang, R., Khan, F., Neto, E. T., Rusli, R., Ji, J. (2020). Could pool fire alone cause a domino effect? Reliability Engineering & System Safety, 202, 106976. doi: 10.1016/j.ress.2020.106976
  4. Reniers, G., Cozzani, V. (2013). 3 – Features of Escalation Scenarios. Elsevier. Domino Effects in the Process Industries, 30–42. doi: 10.1016/B978-0-444-54323-3.00003-8
  5. Liu, J., Li, D., Wang, Z., Chai, X. (2021). A state-of-the-art research progress and prospect of liquid fuel spill fires. Case Studies in Thermal Engineering, 28, 101421. doi: 10.1016/j.csite.2021.101421
  6. Tauseef, S., Abbasi, T., Pompapathi, V., Abbasi, S. (2018). Case studies of 28 major accidents of fires/explosions in storage tank farms in the backdrop of available codes/standards/models for safely configuring such tank farms. Process Safety and Environmental Protection, 120, 331–338. doi: 10.1016/j.psep.2018.09.017
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Delivery trajectory modeling fire extinguishing container to the upper floors of buildings

 

Kalinovsky Andrii

National University of Civil Defenсe of Ukraine

http://orcid.org/0000-0002-1021-5799

 

Kutsenko Leonid

National University of Civil Defenсe of Ukraine

https://orcid.org/0000-0003-1554-8848

 

Polivanov Oleksandr

National University of Civil Defenсe of Ukraine

https://orcid.org/0000-0002-6396-1680

 

Kryvoshei Boris

National University of Civil Defenсe of Ukraine

https://orcid.org/0000-0002-2561-5568

 

Savchenko Olexander

National University of Civil Defenсe of Ukraine

https://orcid.org/0000-0002-1305-7415

 

DOI: https://doi.org/10.52363/2524-0226-2023-38-9

 

Keywords: container, fire extinguishing agent, pulse fire extinguisher, point of intersection of trajectories, minimum starting speed

 

Аnnotation

 

A method is presented for geometrically modeling the trajectory of delivery of a container with a fire extinguishing agent to the windows of the upper floors of houses where a fire occurred. The Typhoon-10 pulse fire extinguisher, which is used as a pneumatic gun, is used as a starting agent. This allows fire extinguishing agents to be delivered to the fire zone discretely, placed in a special container. To determine a rational trajectory for container delivery to the upper floors of the building, differential equations known from mechanics and their solutions were used. The resulting relationships connect the parameters characteristic of the points of the desired trajectory. An addition to these results will be the dependencies found in this work to describe the overhead and floor trajectories that intersect at the point of the burning window of the building. The values of the minimum starting speed for delivering a container to a predetermined window of a building on the required floor have also been determined. It is assumed that for calculations the height of the burning window (from the foundation of the building) is known, and the distance from the pulse fire extinguisher to the wall of the building is also known. Maple was compiled – a program for checking the obtained dependencies by constructing delivery trajecto-ries using computer graphics. The results can be obtained in the form of a table, where the initial speeds and departure angles of the container depend on the floor number of the building. The conducted research is aimed at developing tactics for extinguishing fires in multi-storey buildings using the throwing method (or throwing, using Fire extinguisher Ball). This technology is characterized by the efficiency of fire extinguishing by fire and rescue units, regardless of the condition of the access roads to the building, as well as the existence of various obstacles directly in the yard in front of the house. All this will prevent the spread of fire due to its prompt localization and elimination.

 

References

 

  1. 073: Fire Extinguisher Ball, just throw it in the fire! How to make it. Available at: https://www.hamido.at/fire-ball/
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    edu.ua/handle/123456789/18121
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Development of a fire-proof coating containing silica for polystyrene

 

Lysak Nataliia

National University of Civil Defenсe of Ukraine

https://orcid.org/0000-0001-5338-4704

 

Skorodumova Olga

National University of Civil Defenсe of Ukraine

https://orcid.org/0000-0002-8962-0155

 

Chernukha Anton

National University of Civil Defenсe of Ukraine

https://orcid.org/0000-0002-0365-3205

 

DOI: https://doi.org/10.52363/2524-0226-2023-38-10

 

Keywords: liquid glass, silica-containing coatings, fire protection of building materials, extruded polystyrene foam

 

Аnnotation

 

The possibility of applying a silica-containing coating to the surface of XPS extruded polystyrene foam, which is characterized by a high degree of flammability, was evaluated. The effect of the content and concentration (11, 22, 44 and 85 %) of orthophosphate acid on the optical properties of silicic acid sols obtained by the exchange reaction between aqueous solutions of liquid glass and acetic acid was studied. The fact of incorporation of orthophosphate acid into the gel structure was confirmed by the results of acid-base titration with a sodium hydroxide solution of the intermicellar liquid isolated as a result of gel syneresis. Using an optical microscope, the structure of the polystyrene film coating after treatment with orthophosphate and sulfuric acid solutions was investigated. In both cases, the effect of an increase in the pore area and a general increase in the looseness of the surface was noted, which can help reduce its hydrophobicity and improve adhesion to the coating. The increase in hydrophilicity of the surfaces of polystyrene films after treatment with acids was also confirmed by the flatter, non-spherical shape of the drops of the composition on them. The structure of the obtained coatings on polystyrene films was analyzed. The similarity of the directions of the cracks in the case of treatment of the films with solutions of both acids was noted, and an assumption was made about the presence of uniform deformation stresses during gel shrinkage. A microscopic study of coatings on the surface of extruded polystyrene foam was conducted, and a positive effect of orthophosphate acid on the density of their structure was established. It was determined that the optimal solution for obtaining a uniform coating is the modification of the sol with the help of a 22 % solution of orthophosphate acid. Schemes of the interaction of the silica coating and the polystyrene base in cases of electrostatic interaction and in the case of the formation of covalent bonds between the coating and the polystyrene surface are proposed.

 

References

 

  1. Zhu, Z., Xu, Y., Wang, L., Xu, S., Wang, Y. (2017). Highly Flame Retardant Expanded Polystyrene Foams from Phosphorus–Nitrogen–Silicon Synergistic Adhesives. Industrial & Engineering Chemistry Research, 56(16), 4649–4658. doi: 10.1021/acs.iecr.6b05065
  2. Zhao, W., Zhao, H., Cheng, J., Li, W., Zhang, J., Wang, Y. (2022). A green, durable and effective flame-retardant coating for expandable polystyrene foams. Chemical Engineering Journal, 440, 135807. doi: 10.1016/j.cej.2022.135807
  3. Li, M., Yan, Y., Zhao, H., Jian, R., Wang, Y. (2020). A facile and efficient flame-retardant and smoke-suppressant resin coating for expanded polystyrene foams. Composites Part B: Engineering, 185, 107797. doi: 10.1016/j.compositesb.2020.107797
  4. De Azevedo, A. R. G., França, B. R., Alexandre, J., Marvila, M. T., Zanelato, E. B., De Castro Xavier, G. (2018). Influence of sintering temperature of a ceramic substrate in mortar adhesion for civil construction. Journal of Building Engineering, 19, 342–348. doi: 10.1016/j.jobe.2018.05.026
  5. Greluk, M., Hubicki, Z. (2013). Evaluation of polystyrene anion exchange resin for removal of reactive dyes from aqueous solutions. Chemical Engineering Research and Design, 91(7), 1343–1351. doi: 10.1016/j.cherd.2013.01.019
  6. Zhang, Q., Zhang, Z., Teng, J., Huang, H., Peng, Q., Jiao, T., Hou, L., Li, B. (2015). Highly efficient phosphate sequestration in aqueous solutions using nanomagnesium hydroxide modified polystyrene materials. Industrial & Engineering Chemistry Research, 54(11), 2940–2949. doi: doi.org/10.1021/ie503943z
  7. Du, C., Jia, J., Liao, X., Zhou, L., Hu, Z., Pan, B. (2020b). Phosphate removal by polystyrene anion exchanger (PsAX)-supporting Fe-loaded nanocomposites: Effects of PsAX functional groups and ferric (hydr)oxide crystallinity. Chemical Engineering Journal, 387, 124193. doi: 10.1016/j.cej.2020.124193
  8. Wang, S., Zhang, M., Wang, D., Zhang, W., Liu, S. (2011). Synthesis of hollow mesoporous silica microspheres through surface sol–gel process on polystyrene-co-poly(4-vinylpyridine) core–shell microspheres. Microporous and Mesoporous Materials, 139(1–3), 1–7. doi: 1016/j.micromeso.2010.10.002
  9. Zou, H., Wu, S., Ran, Q., Shen, J. (2008). A simple and Low-Cost method for the preparation of monodisperse hollow silica spheres. Journal of Physical Chemistry C, 112(31), 11623–11629. doi: 10.1021/jp800557k
  10. Mielczarski, J., Jeyachandran, Y., Mielczarski, E., Rai, B. (2011). Modification of polystyrene surface in aqueous solutions. Journal of Colloid and Interface Science, 362(2), 532–539. doi: 10.1016/j.jcis.2011.05.068
  11. Skorodumova, О., Tarakhno, O., Chebotaryova, O., Hapon, Y., Emen, F. (2020). Formation of fire retardant properties in elastic silica coatings for textile materials. Materials Science Forum, 1006, 25–31. doi: 10.4028/www.scientific.net/msf.1006.25
  12. Cox, R. A. (1999). Styrene hydration and stilbene isomerization in strong acid media. An excess acidity analysis. Canadian Journal of Chemistry, 77(5–6), 709–718. doi: 10.1139/v99-028
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  14. Davarnejad, R. (2021). Alkenes – Recent advances, new perspectives and applications. IntechOpen. doi: 10.5772/intechopen.94671

 

Developing a model of the radiating surface of a flame over a flammable liquid spill in the presence of wind

 

Volodymyr Oliinik

National University of Civil Defenсe of Ukraine

http://orcid.org/0000-0002-5193-1775

 

Oleksii Basmanov

National University of Civil Defenсe of Ukraine

http://orcid.org/0000-0002-6434-6575

 

DOI: https://doi.org/10.52363/2524-0226-2023-38-8

 

Keywords: flammable liquid spill, spill fire, radiating flame surface, heat flow

 

Аnnotation

The object of the study is a spill fire. The subject of the study is the geometric characteristics of the flame, in particular, the length and angle of inclination. The model of the radiating surface of a flame over a burning liquid spill of an arbitrary shape is constructed. The essence of the approach is that the length of the flame at a given point is equal to the length of the flame at the point of the circular spill located at the same distance from the boundary of the spill. It allows generalizing the known empirical dependences for the case of spills of arbitrary shape. The flame length is a power-law function of the distance to the spill boundary and the mass loss rate per unit area. To take into account the effect of wind on the shape of the flame, the empirical dependence of the length and angle of inclination of the flame on the wind speed is used. It is assumed that the wind deforms the flame in such a way that all points of the flame surface deviate by the same angle from the vertical. Wind inclines the flame from the vertical axis more significantly for the smaller size of the spill and smaller mass loss rate per unit area. This is due to the formation of more powerful upward currents over the combustion center when its size and intensity of liquid combustion increase. A model of the radiating surface of the flame was constructed in a parametric form. The results obtained from the model are in good agreement with the experimental ones. The relative error for the angle of deviation of the flame by the wind from the vertical axis does not exceed 9%. In practice, this opens up opportunities for calculating the thermal impact on nearby technological objects, as well as determining safe zones for the location of personnel and equipment involved in fire suppression. The model can be used to specify the thermal effect of fire on steel and concrete structures.

 

References

 

  1. Huang, K., Chen, G., Khan, F., Yang, Y. (2021). Dynamic analysis for fire-induced domino effects in chemical process industries. Process Safety and Environmental Protection, 148, 686–697. doi: 10.1016/j.psep.2021.01.042
  2. Hemmatian, B., Abdolhamidzadeh, B., Darbra, R., Casal, J. (2014). The significance of domino effect in chemical accidents. Journal of Loss Prevention in the Process Industries, 29, 30–38. doi: 10.1016/j.jlp.2014.01.003
  3. Fabiano, B., Caviglione, C., Reverberi, A. P., Palazzi, E. (2016). Multicomponent Hydrocarbon Pool Fire: Analytical Modelling and Field Application. Chemical Engineering Transactions, 48, 187–192. doi: 10.3303/CET1648032
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